Install Playonlinux in Synaptic.
Tools -> Manage Wine Version -- Wine Versions tab; you can download and install different versions of Wine you need.
After that, install Windows applications you need, you can either
download the apps from PlayOnLinux repository or manually install from
installation file by clicking install a.pol package or an unsupported application and follow the steps.
After Windows application installations, you can manage which Wine
version to run which application on Tools -> Manage Wine Versions --
My Applications tab. Click the application and choose the Wine version
on the drop box below it.